A client of mine was having an issue because originally within their server build, they were hard coding the NTP server into the registry. Well that NTP server has now gone away and they wanted to use Active Directories model of using the DC within their site configuration to pull the time from. Here is a script I used to stop w32time service, reregister w32tm, start w32time service and resync with AD. This worked great and the client was happy.
net stop w32time
w32tm /unregister
w32tm /register
net start w32time
w32tm /resync
